No, I asked Geeg when she was here and she said no. Something to do with the colours actually cure at different times but they say two minutes/60 seconds LED as it's all encompassing and you can't over cure. If they had to specify which colours need what time it would get confusing and potentially cause problems with under curing, etc.
So only layering as Noodle says, I do know techs who are mixing pre application and say their not having issues but the second it chipped/peeled/whatever I'd lose faith